Astronomy & Celestial Mechanics
the sky, computed
Concept

Collisional excitation — where it appears

The lifting of an atom or ion to a higher energy level by the impact of a free electron rather than by a photon. Its rate depends on the density of colliders and the temperature of the gas, and in thin nebulae each event is usually followed by a line photon that escapes.

Named by 2 essays across one field — each of them below, with the objects they name alongside it.

An absorption line made by scattering alone. Emergent line profiles, as a fraction of the continuum, against distance from line centre in Doppler widths, for a strong line — 10⁵ times the continuum opacity at its centre — in an atmosphere at one temperature throughout, for destruction probabilities ε = 0.01, 10⁻⁴, 10⁻⁶. In local thermodynamic equilibrium this atmosphere makes no line at all: every depth radiates at the same temperature, and the line's extra opacity merely moves the depth from which the light comes. With scattering the line is deep, its central intensity 0.198, 0.021, 0.002 of the continuum, about twice √ε. The darkness is not a low temperature anywhere; it is photons scattered out of the line and back into the gas until they are destroyed or escape through the continuum, never reaching the observer at the line's frequency.

A line darker than any temperature in the gas

An absorption line is usually read as a temperature: the line is dark because its light comes from higher, cooler gas. A strong resonance line breaks that reading. Its photons are scattered thousands of times before a collision can destroy them, so near the surface the line's source function falls to the square root of the destruction probability times the Planck function — and even a gas at one temperature throughout shows a line almost black at its centre.

starlight · Spectra Whether an excited ion radiates depends only on what reaches it first. The rate per second at which an oxygen ion in the state that gives the 5007 Å line loses its energy, by radiating and by collision, against electron density, both logarithmic. Radiating takes about 51 seconds whatever the surroundings. Collisions speed up with density and cross at 6.8e+5 per cubic centimetre. The air at the Earth's surface, 2.7×10¹⁹ molecules per cubic centimetre, has a collision rate about 4×10¹³ times the radiative one, so the ion loses its energy without radiating. A nebula at 10⁴ per cubic centimetre is sixty times below the crossing. The line has a tiny transition probability; the atom was never forbidden to make it, and it requires only the emptiness in which there is time.

An element that was only empty space

In 1864 William Huggins turned a spectroscope on a planetary nebula and saw a bright green line that matched nothing on Earth. It was given a name, nebulium, and it was treated as a new element for sixty years, until the periodic table had no room left for it. In 1927 Ira Bowen showed it was ordinary oxygen, emitting by a route that collisions close long before any laboratory vacuum could reach it. The line was never forbidden. It simply needs about a minute of being left alone, and nothing on Earth gets that.

starlight · Spectra

Named alongside it

The objects these essays reach for when they reach for this one.

Absorption lineCritical densityEddington barbier relationElectron temperatureForbidden lineLocal thermodynamic equilibriumMetastable stateNebuliumNon-LTEPlanetary nebulaScatteringSource function

All concepts