Astronomy & Celestial Mechanics
the sky, computed
Concept

Pseudo continuum — where it appears

The apparent baseline of a spectrum crowded with overlapping molecular bands, which is the tops of the strongest absorbers rather than the true continuous opacity. Every equivalent width measured against it is a different quantity from the one theory describes.

Named by 2 essays across one field — each of them below, with the objects they name alongside it.

A continuum drawn 4.3 per cent below the real one. A short stretch of spectrum with one strong line in it and 150 weak ones scattered across the same interval. The upper dashed line is the true continuum — the flux the star would emit with no lines at all — and it is not observable. The lower one is what a fit through the highest points of the spectrum returns, which is 4.3 per cent lower, because the weak lines have depressed the gaps between the strong ones. Measuring the strong line's equivalent width against the apparent continuum instead of the real one makes it 11.2 per cent too small. The error has a sign, it is worse in spectra with more lines, and it therefore correlates with metallicity — which is exactly the quantity being measured.

A continuum that was never observed

An equivalent width is an area measured relative to the continuum, and the continuum is not in the data. It is drawn — a curve through the highest points of the spectrum — and in any spectrum with many weak lines those highest points are already below the true continuum, because the weak lines have eaten the gaps.

starlight · Line formation Where titanium oxide comes apart, and what the pressure does to it. The fraction of titanium oxide dissociated into Ti + O, against temperature, for a gas of equal parts at 10, 300, 6000 N/m² of total pressure. The equilibrium is Saha's with a free atom in place of the free electron and the pair's reduced mass in place of the electron's — the two atoms' partial pressures multiplied together, divided by the molecule's, equal an equilibrium constant Kₚ(T) — which for equal abundances gives a dissociated fraction of √(Kₚ/(Kₚ+P)) exactly. A molecule is one particle becoming two, so pressure suppresses the reaction exactly as it suppresses ionisation — the half-dissociation point moves from 3145 K at 10 N/m² to 4164 K at 6000. The bond energy is 6.87 eV against hydrogen's ionisation potential of 13.6, which is why this happens at a third of the temperature. Rotational and vibrational partition functions are included, classically and harmonically; the atoms keep their ground-term weights.

A spectrum with no continuum left in it

Below about four thousand kelvin a photosphere stops being a gas of atoms. Titanium oxide, water and carbon monoxide take over, the same equilibrium settles how much of each survives with a bond energy where an ionisation potential used to be — and the bands are so crowded that the level every line depth is measured against is nowhere on the plate.

starlight · Ionisation

Named alongside it

The objects these essays reach for when they reach for this one.

Abundance analysisBond energyContinuum normalisationCurve of growthDifferential analysisDissociation equilibriumElectron pressureEquivalent widthLine blanketingLuminosity classMetallicityMolecular band

All concepts