Astronomy & Celestial Mechanics
the sky, computed
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Ionisation — the series

4 essays on one idea, from the one that introduces it to the one that assumes the rest.
  1. The Balmer maximum is at 9,870 K, and it is a maximum in temperature. What two absorption lines actually count, each normalised to its own maximum. The first curve is the fraction of all hydrogen sitting in n = 2 — the only hydrogen a Balmer line can absorb — which is a Boltzmann factor climbing with temperature multiplied by the neutral fraction falling with it. The product peaks at 9,870 K, where 35.2% of the hydrogen is still neutral and only 8.73·10⁻⁶ of all of it is in n = 2 at all. Below the peak there is plenty of hydrogen and almost none of it excited; above it there is plenty excited and almost none of it neutral. The second curve is the fraction of calcium that is singly ionised, which is what the Ca II K line counts, and it peaks at 6,335 K — cooler, because calcium gives up its first electron at 6.113 eV. At 6,000 K the Balmer curve is at 0.1% of its own maximum while Ca II is near its peak, and calcium is 4.5·10⁵ times rarer than hydrogen in the same gas. A spectrum in which Ca II K is the strongest line is not a spectrum of a calcium star. Reading it as one is precisely the error that had the Sun made of iron until 1925.

    Why hydrogen's lines are strongest where hydrogen is not

    A Balmer line counts the hydrogen atoms sitting in one particular excited state, and that population peaks near 10,000 K — where a third of the hydrogen has already been ionised away. The strength of a line is a thermometer, and reading it as an abundance put hydrogen at one per cent of the Sun until 1925.

    part 1 · starlight
  2. 742 kelvin between a dwarf and a supergiant, at the same ionisation. The fraction of calcium still neutral against temperature, for three surface gravities: a dwarf, a giant and a supergiant. The three curves are the same curve slid sideways. The Saha equation carries the electron pressure in its denominator, and the photospheric pressure follows the surface gravity as its square root — hydrostatic equilibrium gives a gas pressure of order g over the opacity, and the opacity in a cool star is set by the electrons themselves. So the pressure runs from 19 newtons a square metre in the dwarf down to 0.48 in the supergiant, a factor of 40, and the half-ionisation point moves from 4427 kelvin to 3685 — 742 kelvin apart. At fixed temperature the ionisation ratio goes as g^-0.50, exactly the square root the algebra requires. A star's luminosity class is a measurement of the density of its photosphere, read off which stage of an element the lines belong to.

    A luminosity class is a density measurement

    The Saha equation has an electron pressure in its denominator, and a supergiant's photosphere is forty times less dense than a dwarf's at the same temperature. So the same element sits in different ionisation stages in the two, the spectrum says which, and the second axis of stellar classification is a barometer.

    part 2 · starlight
  3. Where titanium oxide comes apart, and what the pressure does to it. The fraction of titanium oxide dissociated into Ti + O, against temperature, for a gas of equal parts at 10, 300, 6000 N/m² of total pressure. The equilibrium is Saha's with a free atom in place of the free electron and the pair's reduced mass in place of the electron's — the two atoms' partial pressures multiplied together, divided by the molecule's, equal an equilibrium constant Kₚ(T) — which for equal abundances gives a dissociated fraction of √(Kₚ/(Kₚ+P)) exactly. A molecule is one particle becoming two, so pressure suppresses the reaction exactly as it suppresses ionisation — the half-dissociation point moves from 3145 K at 10 N/m² to 4164 K at 6000. The bond energy is 6.87 eV against hydrogen's ionisation potential of 13.6, which is why this happens at a third of the temperature. Rotational and vibrational partition functions are included, classically and harmonically; the atoms keep their ground-term weights.

    A spectrum with no continuum left in it

    Below about four thousand kelvin a photosphere stops being a gas of atoms. Titanium oxide, water and carbon monoxide take over, the same equilibrium settles how much of each survives with a bond energy where an ionisation potential used to be — and the bands are so crowded that the level every line depth is measured against is nowhere on the plate.

    part 3 · starlight
  4. Where a photosphere's free electrons come from. The share of the free electrons donated by metals rather than by hydrogen, against temperature, at a gas pressure of 12000 N/m² and at solar abundance, 1 dex below solar, 2 dex below solar. The electron pressure is not assumed here — it is solved for, as the value at which the ionisation of the gas supplies exactly the electrons the gas contains. Below about 5897 K at solar abundance every free electron in the gas comes from an element present at one part in ten thousand, because hydrogen's 13.6 eV keeps it neutral while magnesium's 7.6 does not. The handover is fast: solar crosses a half at 5897 K, 1 dex down crosses a half at 5088 K, 2 dex down crosses a half at 4467 K. At 5,772 K and this pressure the solved electron pressure is 1.78 N/m².

    The continuum is made by one atom in ten thousand

    The Sun's light leaves through an ion that exists only because a hydrogen atom will hold a second electron by three-quarters of an electronvolt. The electrons it holds come almost entirely from magnesium, silicon and iron — so the level against which every solar line depth is measured is rationed by elements present at one part in ten thousand.

    part 4 · starlight

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