Spectra — the series
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Composition, read from what is missing
The dark lines in a stellar spectrum are wavelengths that never arrived. Which ones are absent names the elements present — and the strength of a line says more about temperature than about abundance.
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The second thing a spectrum says
Two stars of the same colour can differ in luminosity by ten magnitudes, and the difference shows in the widths of their lines rather than in which lines are present. That width is a pressure, the pressure is a gravity, and the gravity is a distance.
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A temperature and a gravity that trade against each other
A stellar spectrum contains the star's temperature, its surface gravity and its composition, and no single feature in it contains only one of the three. Every diagnostic is a band in the parameter plane rather than a point, and the answer is where the bands cross — which makes choosing diagnostics that disagree in their sensitivities the whole of the art.
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A line darker than any temperature in the gas
An absorption line is usually read as a temperature: the line is dark because its light comes from higher, cooler gas. A strong resonance line breaks that reading. Its photons are scattered thousands of times before a collision can destroy them, so near the surface the line's source function falls to the square root of the destruction probability times the Planck function — and even a gas at one temperature throughout shows a line almost black at its centre.
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A width that knows how bright the star is
In the dark trough of a cool star's calcium K line sits a small bright emission core made in its chromosphere. In 1957 Olin Wilson and Vainu Bappu found that the core's width predicts the star's absolute magnitude over fifteen magnitudes — from dwarfs to supergiants, whatever the star's temperature and however active its chromosphere — and the simplest physical account of why reproduces the relation's existence and misses its slope by half.
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An element that was only empty space
In 1864 William Huggins turned a spectroscope on a planetary nebula and saw a bright green line that matched nothing on Earth. It was given a name, nebulium, and it was treated as a new element for sixty years, until the periodic table had no room left for it. In 1927 Ira Bowen showed it was ordinary oxygen, emitting by a route that collisions close long before any laboratory vacuum could reach it. The line was never forbidden. It simply needs about a minute of being left alone, and nothing on Earth gets that.