Twilight — the series
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Three definitions of night
Twilight ends at three different depression angles, and each threshold is a statement about what can no longer be done. Its length is not a duration but a rate — how fast the Sun goes down — and above one latitude the deepest of the three never arrives at all.
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The shadow that climbs the zenith
After sunset the sky overhead is lit only above the Earth's own shadow, and the shadow climbs as the square of the Sun's depression. Scattering computed once from that geometry predicts a sky that dims faster and faster and is as dark as night by nine degrees. The real sky takes eighteen, and the difference is light that has been scattered more than once.
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Ozone keeps the twilight zenith blue
After sunset the sky overhead turns a deep blue, and scattering alone cannot explain it. The light that reaches the zenith has first grazed hundreds of kilometres of air, which strips blue out of the sunlight as fast as scattering puts it back, and the two very nearly cancel. What tips the balance is a gas that makes up a few parts in ten million of the atmosphere and absorbs the orange and red end of the spectrum.
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The air's height against the planet sets the twilight
On the Earth the sky overhead fades over about nine degrees of the Sun's descent. That angle is not a property of air or of sunlight. It is the square root of twice the height of the scattering layer divided by the radius of the planet, and on a small world with a tall haze it grows to tens of degrees — so that twilight on Titan lasts more than a day.