White dwarf cooling — the series
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A clock with no fuel in it
A white dwarf has nothing left to burn, so its brightness is a record of how long it has been cooling. The faintest ones in the Galaxy are not faint because they are small — they are as faint as anything has had time to become, and the place where they stop is a date.
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A clock that stops while its interior freezes
A white dwarf has nothing left to burn, so its brightness is a record of how long it has been cooling — until the interior crystallises. The latent heat of that phase change, and the settling of a heavy isotope through what is left, hold a massive white dwarf up for nearly three extra billion years.
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A colour that runs backwards at the end of cooling
A white dwarf reddens as it cools, like every other hot body — until its surface falls below about four thousand kelvin. Then pairs of hydrogen molecules, colliding in an atmosphere dense enough to crush them together, begin to absorb its infrared light, and the star turns blue again while it goes on getting fainter. The oldest white dwarfs in the Galaxy have the colours of young ones, and for years they were looked for in the wrong place.
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A star that distils itself as it freezes
A carbon–oxygen white dwarf does not freeze at one composition. The crystals that form at its centre take more oxygen than the liquid they form from, the carbon-rich liquid left behind is lighter and rises, and the star slowly sorts its own interior, oxygen down and carbon up. The gravitational energy that releases is radiated at a luminosity so faint that it holds the star up for about a billion years — a delay comparable to the latent heat of freezing, and one of the larger uncertainties in every white-dwarf age.