Abundance degeneracy — where it appears
Named by 2 essays across one field — each of them below, with the objects they name alongside it.
A spectrum flattened by cloud, or by nothing
A transmission spectrum measures how a planet's apparent radius changes with wavelength, and never the radius itself. That missing level is a free parameter, it trades almost exactly against the abundance of whatever is absorbing, and a cloud deck adds a third unknown to a curve that constrains two.
Molecules seen only through a change of temperature
The heat a planet gives off, measured colour by colour as it disappears behind its star, carries the fingerprints of the molecules in its atmosphere — but only because the atmosphere's temperature changes with height. Water absorbs where the air cools upward and emits where it warms, and in an atmosphere at one temperature every molecule vanishes from the spectrum, however much of it there is. An emission spectrum is a sounding of a temperature gradient, and the molecules are what it is taken with.
Named alongside it
The objects these essays reach for when they reach for this one.
Bayesian inferenceBrightness temperatureCloud deckContribution functionEmission spectrumGrey opacityMean molecular weightRayleigh scatteringReference radiusRetrievalScale heightSecondary eclipse