Concept

Rayleigh scattering — where it appears

Scattering by particles far smaller than the wavelength, whose cross-section goes as the inverse fourth power and which is what the air itself does. It polarises the scattered light perpendicular to the scattering plane, maximally at a right angle, which is what makes the daytime sky's polarisation a map of the Sun's position.

Named by 10 essays across 3 fields — each of them below, with the objects they name alongside it.

The Bouguer line, and the intercept nobody observed. Instrumental magnitude against airmass for one star of magnitude 10 outside the atmosphere, observed at 5 airmasses in 5 bands. Each slope is that band's extinction coefficient, computed from Rayleigh scattering, an aerosol term and ozone rather than assumed: U 0.493, B 0.246, V 0.126, R 0.061, I 0.027 magnitudes per airmass. Every line is fitted through its points and extended to X = 0, and the intercept there is the published magnitude — a measurement made at an airmass no observation is ever taken at, because the smallest airmass available is 1 and that is already a whole atmosphere. Two consequences follow and neither is a detail. The slope has to be re-measured every night, because the aerosol term changes with the weather and is not a property of the site. And the U-band line is 3.9 times steeper than the V-band one, so the extrapolation is 3.9 times longer in exactly the band where photons are scarcest — which is why ultraviolet photometry from the ground was always the least trustworthy part of a magnitude system.

A magnitude measured where nothing was measured

Every published brightness is an extrapolation off the end of a graph. A star is observed through one atmosphere at least, a line is fitted against airmass, and the number quoted is its intercept at zero — a place no observation is ever taken from.

starlight · Extinction
A radius that depends on the colour it is measured in. Transit depth against wavelength for a planet of 1.38 Jupiter radii at 1400 K, whose atmosphere has a scale height of 538 km — computed from H = kT/µg, not assumed. One scale height of extra opacity adds 153 parts per million to a transit of 1.40 per cent, so the whole spectral signal is 862 ppm at its strongest: one part in 16 of the transit that carries it. The features are at real band centres — sodium at 0.589 µm, water at 1.4 µm, carbon dioxide at 4.3 µm — with the rise at the blue end the Rayleigh slope of scattering off the smallest particles.

A radius that depends on the colour it is measured in

Measure a transit in one colour and then another, and the planet is a different size. The difference is a few atmospheric scale heights, which is a few hundred parts per million of an already tiny signal.

exoplanets · Exoplanet atmospheres
Three planets that are the same spectrum. A model transmission spectrum, in scale heights of apparent radius, drawn three times: once as it is, once with the reference radius raised by 0.45 scale heights and the abundance reduced to compensate, and once with a cloud deck truncating the features. The three differ by 0.21 scale heights root-mean-square against features of 2.1, which is well inside the error bars of any real observation. The reason is structural rather than observational: a transmission spectrum measures a difference in apparent radius with wavelength and never an absolute radius, so the level is a free parameter, and shifting the level trades against the abundance almost exactly. Adding a cloud deck adds a third parameter that flattens features and trades against both. Three unknowns and one curve is why the quoted abundance uncertainties from transmission spectroscopy are so much larger than the photometric precision suggests.

A spectrum flattened by cloud, or by nothing

A transmission spectrum measures how a planet's apparent radius changes with wavelength, and never the radius itself. That missing level is a free parameter, it trades almost exactly against the abundance of whatever is absorbing, and a cloud deck adds a third unknown to a curve that constrains two.

exoplanets · Exoplanet atmospheres
The zenith sky after sunset, as single scattering predicts it. The brightness of the zenith sky at 550 nm, in magnitudes per square arcsecond with brighter upward, against the Sun's depression below the horizon, computed by single scattering in a spherical atmosphere: US Standard Atmosphere densities, Rayleigh scattering, a 300 Dobson-unit ozone layer, and every photon scattered exactly once. The Earth's shadow climbs the zenith as R(sec d − 1) — 8.7 km at 3°, 35.1 at 6°, 142 at 12° — through air that thins by a factor of e every eight kilometres or so, so the brightness does not fall steadily: it falls 1.4 magnitudes a degree between 3° and 6°, and 2.7 a degree between 7° and 10°. The model gives 14.3 at the end of civil twilight and 27.0 at the end of nautical. The dashed line is the natural night sky, 21.9 magnitudes per square arcsecond. Single scattering reaches it at 9.25° of depression — 8.8 degrees before the 18° at which astronomical twilight is observed to end. The difference is not an error in the arithmetic; it is the light this model leaves out, scattered more than once.

The shadow that climbs the zenith

After sunset the sky overhead is lit only above the Earth's own shadow, and the shadow climbs as the square of the Sun's depression. Scattering computed once from that geometry predicts a sky that dims faster and faster and is as dark as night by nine degrees. The real sky takes eighteen, and the difference is light that has been scattered more than once.

sky · Twilight
The colour of the zenith at twilight, with and without ozone. The colour of the zenith sky relative to sunlight — the 450 nm brightness against the 650 nm brightness, in magnitudes, bluer upward — against the Sun's depression, computed by single scattering with a 300 Dobson-unit ozone layer and again with none. Scattering alone favours blue by λ⁻⁴, which would make the sky 1.60 magnitudes bluer than sunlight if nothing were removed on the way; that is the dotted line. But after sunset every ray has travelled a long grazing path, and Rayleigh scattering removes blue from that path faster than red, so the two effects fight. Without ozone they very nearly cancel: the zenith is 0.01 magnitudes from sunlight's own colour at sunset and 0.06 at 6° — a pale, colourless sky — and only turns bluer, −0.13 at 10°, once the lit layer has climbed above most of the air the grazing ray used to cross. With ozone the zenith is −0.34 at sunset, −0.67 at 6° and −0.76 at 10°: bluer than without by 0.72 magnitudes at 6°, because the grazing ray also crosses the ozone layer near its tangent point, and ozone's Chappuis band absorbs orange and red rather than blue. The ozone cross-sections are approximate, and the conclusion does not depend on them to better than a factor of two.

Ozone keeps the twilight zenith blue

After sunset the sky overhead turns a deep blue, and scattering alone cannot explain it. The light that reaches the zenith has first grazed hundreds of kilometres of air, which strips blue out of the sunlight as fast as scattering puts it back, and the two very nearly cancel. What tips the balance is a gas that makes up a few parts in ten million of the atmosphere and absorbs the orange and red end of the spectrum.

sky · Twilight
The extinction curve of a mixture, and of single sizes. Extinction relative to the V band against inverse wavelength, from the infrared at 0.3 inverse microns to the near ultraviolet at 3.3. The thick grey curve is the observed Galactic average, the Cardelli–Clayton–Mathis law at Rᵥ = 3.1. The coloured curves are computed: MRN, 0.005–0.25 µm, Rᵥ = 2.4; all grains 0.05 µm, Rᵥ = 1.8; all grains 0.3 µm, Rᵥ = 18.4. Grains of any single size make a curve with a knee: steep where the wavelength is longer than the grain, flat where it is shorter. Only a spread of sizes, with many more small grains than large ones, makes the nearly straight rise with inverse wavelength that is observed, and the first model follows the observed curve to an r.m.s. of 0.19 in these units. The ultraviolet bump beyond this range needs a separate population of small carbonaceous grains and is not modelled.

A size read from the slope of a colour

Interstellar dust dims blue light more than red, and the way the dimming rises toward the blue is nearly a straight line in inverse wavelength. No grain of any single size makes that line. A grain only removes light selectively when it is comparable in size to the wavelength, so the extinction curve read across wavelength is the population of grains read across size — and it says there are vastly more small grains than large ones, in the same proportion that grinding rocks together produces.

starlight · Extinction
The zenith sky after sunset, with light scattered twice. The brightness of the zenith sky at 550 nm in magnitudes per square arcsecond, brighter upward, against the Sun's depression: light scattered once (dashed), light scattered twice (dash-dot), and their sum (solid), in a spherical atmosphere with US Standard densities, Rayleigh scattering and 300 Dobson units of ozone. The dashed horizontal line is the natural night sky, 21.9 magnitudes per square arcsecond. Once-scattered light reaches it at 9.2°; the sum, dominated beyond about seven degrees by light scattered twice, reaches it at 13.2°, and it falls to a hundredth of the night sky — five magnitudes fainter, about the smallest excess a careful measurement of the sky can detect — at 17.5°, where once-scattered light alone would have reached that level at 11.9°. The second order falls more slowly than the first because it can reach the zenith by two grazing hops — sunlight to the lit air low towards the Sun, and that air to the shadowed air overhead — each of which needs only part of the depression a single hop would. Orders beyond the second are left out, so the solid curve is a lower bound on the sky.

The night is late because the light bounces twice

Light scattered once can reach the zenith only while the Earth's shadow over the observer is still low in the air, and by that reckoning the sky should reach the darkness of night about nine degrees after sunset. It does not until eighteen. The difference is light scattered twice — first by the sunlit air hundreds of kilometres towards the sunset, then again by the shadowed air overhead — and adding it to the calculation moves the end of twilight almost exactly to where observers have always put it.

sky · Twilight
How much light a fixed mass of dust scatters, as its largest grains grow. The scattering cross-section per unit mass of dust, on a logarithmic scale relative to the largest value drawn, against the size of the largest grains in a power-law distribution n(a) ∝ a^−3.5 from 0.005 µm, at wavelengths of 1.25, 2.2, 3.6 µm. With the largest grains at a quarter of a micron — the size the interstellar extinction curve implies — the dust scatters 3.6 µm light 33 times less efficiently than it does once they reach a micron: grains much smaller than the wavelength scatter as the fourth power of their size over the wavelength and are all but invisible. At 3.6 µm the scattering per mass peaks when the largest grains are 3.5 µm, and falls beyond, as the mass moves into grains too large to scatter efficiently per gram. A dense core that glows at 3.6 µm in scattered starlight is therefore a core whose grains have grown to a micron or more.

A glow that weighs the grains reddening cannot see

The interstellar extinction curve reads the sizes of dust grains from how much more they dim blue light than red, and it goes blind at the top end: grains larger than about a micron dim every visible colour alike. Those are the grains that hold most of the mass, and the ones from which planets begin. Dense cloud cores glowing faintly at 3.6 microns in scattered starlight are the first direct sign of them — because only grains grown to a micron or more scatter that light at all.

starlight · Extinction
The polarised light HD 189733 b can send. The polarised part of HD 189733 b's reflected light, as a fraction of its star's light in parts per million, against orbital phase from one transit to the next, for an orbit of radius 0.0314 AU, a planet of 1.138 Jupiter radii and an inclination of 85.7°. A planet's reflected light is its geometric albedo times (R/a)² — here 3·10⁻⁴ — times a phase function, and the polarised part is that times the degree of polarisation, which for a scattering atmosphere peaks near quadrature where the planet is half lit. With an albedo of 0.4 and a peak polarisation of 0.5 the signal reaches 24 ppm (solid). The ceiling (dashed) gives the planet the largest albedo a scattering atmosphere can have, 0.75, and perfect polarisation: 91 ppm. An amplitude of 100 ppm (dotted), the order of the signal claimed in 2008, would need the planet to reflect and polarise more light than falls on it.

A polarisation capped by the light the planet catches

Light scattered by a planet's atmosphere is polarised, most strongly when the planet is half lit, and the polarisation angle turns as the planet orbits — so a planet's polarised light would weigh its atmosphere and draw its orbit on the sky without a transit. In 2008 it was reported for a hot Jupiter at a part in ten thousand of its star's light. That amplitude is more than the planet can send: no atmosphere reflects more than three-quarters of the light that falls on it or polarises more than all of it, and the light that falls on it is set by its size and its distance. The photons for a real detection are cheap; what limits it is a polarimeter stable to a part in a million.

sky · Apparent motion
Rays from a ring of sunsets, bent into the shadow. Sunlight grazing the Earth at heights of 1, 5, 15 km, bent toward the axis by the atmosphere by twice the refraction at that height, reaching the Moon's distance, with the shadow's geometry in the plane through the Sun: the distance axis is compressed by about sixty to one against the vertical. The low rays cross the axis well before the Moon and reach the far side of the shadow; the higher rays only bend enough to enter its edge. The geometric umbra at the Moon has a radius of 4584 km, the two dashed lines, so without air the Moon would disappear inside it. Light arrives from the whole ring round the Earth, which is every sunrise and sunset at that moment.

A Moon lit by every sunset at once

With no air, the Moon would vanish inside the Earth's shadow. Instead it turns a dull copper, because the atmosphere bends sunlight round the planet, and what reaches the Moon has gone through a ring containing every sunrise and sunset on Earth at that moment. Each height in the air lights one place in the shadow, so the colour across the disc is a map of the atmosphere by altitude. It has sometimes been black, after the largest volcanoes, and that makes a century of eclipse records a measurement of the stratosphere older than any instrument sent up to sample it.

sky · Phases and eclipses

Named alongside it

The objects these essays reach for when they reach for this one.

OzoneScale heightOptical depthTwilightEarth shadowExtinctionGrain size distributionInterstellar dustMean molecular weightMultiple scatteringSingle scatteringSky brightness

All concepts