Concept

Ozone — where it appears

Triatomic oxygen, concentrated in a stratospheric layer peaking near 22 kilometres. It absorbs ultraviolet light strongly and orange and red light weakly, in the Chappuis band, which along the grazing path of twilight sunlight is what turns the zenith blue.

Named by 4 essays across 2 fields — each of them below, with the objects they name alongside it.

The Bouguer line, and the intercept nobody observed. Instrumental magnitude against airmass for one star of magnitude 10 outside the atmosphere, observed at 5 airmasses in 5 bands. Each slope is that band's extinction coefficient, computed from Rayleigh scattering, an aerosol term and ozone rather than assumed: U 0.493, B 0.246, V 0.126, R 0.061, I 0.027 magnitudes per airmass. Every line is fitted through its points and extended to X = 0, and the intercept there is the published magnitude — a measurement made at an airmass no observation is ever taken at, because the smallest airmass available is 1 and that is already a whole atmosphere. Two consequences follow and neither is a detail. The slope has to be re-measured every night, because the aerosol term changes with the weather and is not a property of the site. And the U-band line is 3.9 times steeper than the V-band one, so the extrapolation is 3.9 times longer in exactly the band where photons are scarcest — which is why ultraviolet photometry from the ground was always the least trustworthy part of a magnitude system.

A magnitude measured where nothing was measured

Every published brightness is an extrapolation off the end of a graph. A star is observed through one atmosphere at least, a line is fitted against airmass, and the number quoted is its intercept at zero — a place no observation is ever taken from.

starlight · Extinction
The zenith sky after sunset, as single scattering predicts it. The brightness of the zenith sky at 550 nm, in magnitudes per square arcsecond with brighter upward, against the Sun's depression below the horizon, computed by single scattering in a spherical atmosphere: US Standard Atmosphere densities, Rayleigh scattering, a 300 Dobson-unit ozone layer, and every photon scattered exactly once. The Earth's shadow climbs the zenith as R(sec d − 1) — 8.7 km at 3°, 35.1 at 6°, 142 at 12° — through air that thins by a factor of e every eight kilometres or so, so the brightness does not fall steadily: it falls 1.4 magnitudes a degree between 3° and 6°, and 2.7 a degree between 7° and 10°. The model gives 14.3 at the end of civil twilight and 27.0 at the end of nautical. The dashed line is the natural night sky, 21.9 magnitudes per square arcsecond. Single scattering reaches it at 9.25° of depression — 8.8 degrees before the 18° at which astronomical twilight is observed to end. The difference is not an error in the arithmetic; it is the light this model leaves out, scattered more than once.

The shadow that climbs the zenith

After sunset the sky overhead is lit only above the Earth's own shadow, and the shadow climbs as the square of the Sun's depression. Scattering computed once from that geometry predicts a sky that dims faster and faster and is as dark as night by nine degrees. The real sky takes eighteen, and the difference is light that has been scattered more than once.

sky · Twilight
The colour of the zenith at twilight, with and without ozone. The colour of the zenith sky relative to sunlight — the 450 nm brightness against the 650 nm brightness, in magnitudes, bluer upward — against the Sun's depression, computed by single scattering with a 300 Dobson-unit ozone layer and again with none. Scattering alone favours blue by λ⁻⁴, which would make the sky 1.60 magnitudes bluer than sunlight if nothing were removed on the way; that is the dotted line. But after sunset every ray has travelled a long grazing path, and Rayleigh scattering removes blue from that path faster than red, so the two effects fight. Without ozone they very nearly cancel: the zenith is 0.01 magnitudes from sunlight's own colour at sunset and 0.06 at 6° — a pale, colourless sky — and only turns bluer, −0.13 at 10°, once the lit layer has climbed above most of the air the grazing ray used to cross. With ozone the zenith is −0.34 at sunset, −0.67 at 6° and −0.76 at 10°: bluer than without by 0.72 magnitudes at 6°, because the grazing ray also crosses the ozone layer near its tangent point, and ozone's Chappuis band absorbs orange and red rather than blue. The ozone cross-sections are approximate, and the conclusion does not depend on them to better than a factor of two.

Ozone keeps the twilight zenith blue

After sunset the sky overhead turns a deep blue, and scattering alone cannot explain it. The light that reaches the zenith has first grazed hundreds of kilometres of air, which strips blue out of the sunlight as fast as scattering puts it back, and the two very nearly cancel. What tips the balance is a gas that makes up a few parts in ten million of the atmosphere and absorbs the orange and red end of the spectrum.

sky · Twilight
Rays from a ring of sunsets, bent into the shadow. Sunlight grazing the Earth at heights of 1, 5, 15 km, bent toward the axis by the atmosphere by twice the refraction at that height, reaching the Moon's distance, with the shadow's geometry in the plane through the Sun: the distance axis is compressed by about sixty to one against the vertical. The low rays cross the axis well before the Moon and reach the far side of the shadow; the higher rays only bend enough to enter its edge. The geometric umbra at the Moon has a radius of 4584 km, the two dashed lines, so without air the Moon would disappear inside it. Light arrives from the whole ring round the Earth, which is every sunrise and sunset at that moment.

A Moon lit by every sunset at once

With no air, the Moon would vanish inside the Earth's shadow. Instead it turns a dull copper, because the atmosphere bends sunlight round the planet, and what reaches the Moon has gone through a ring containing every sunrise and sunset on Earth at that moment. Each height in the air lights one place in the shadow, so the colour across the disc is a map of the atmosphere by altitude. It has sometimes been black, after the largest volcanoes, and that makes a century of eclipse records a measurement of the stratosphere older than any instrument sent up to sample it.

sky · Phases and eclipses

Named alongside it

The objects these essays reach for when they reach for this one.

Rayleigh scatteringSingle scatteringTwilightAerosolAirmassAtmospheric extinctionAtmospheric refractionBouguer lineChappuis bandColour indexColour termDanjon scale

All concepts