Concept

Spectral classification — where it appears

The placing of a star in the sequence O B A F G K M and a luminosity class, from the strengths and widths of lines and with no distance needed. The first axis is temperature and the second is surface gravity, and together they give an absolute magnitude — a distance obtained from a spectrum alone.

Named by 6 essays across one field — each of them below, with the objects they name alongside it.

An absorption spectrum at 5772 K. A blackbody continuum at 5772 K with absorption lines cut out of it, each line's depth computed from how much of the gas is in a state that can absorb it. 8 of the 8 lines are strong enough to see at this temperature, which is the whole reason the spectral sequence is a temperature sequence.

Composition, read from what is missing

The dark lines in a stellar spectrum are wavelengths that never arrived. Which ones are absent names the elements present — and the strength of a line says more about temperature than about abundance.

starlight · Spectra
B − V against temperature, computed and measured. B − V against effective temperature. The curve is the colour index of a blackbody, obtained by integrating Planck's law against B and V response functions and subtracting a constant so that the index is exactly zero at 9600 K — the convention that an A0V star has every colour index zero, which is a choice and not a measurement. The 15 points are the main sequence as it is actually measured, and they do not lie on the curve: at the Sun's temperature the blackbody gives 0.446 where the sky gives 0.653, and at M0V 0.995 against 1.40. The model is too blue almost everywhere, and least wrong near 9600 K — which is why the zero point is put where it is. A colour index is a difference of two magnitudes, so it is a difference of two integrals, and changing either filter changes the number.

A magnitude has to say which light

The same star is a different magnitude in every filter, and a colour index is a difference of two conventions rather than a property of the star. Both are integrals of a spectrum against a piece of glass, and the zero point is a choice somebody made in 1953.

starlight · Photometric systems
Three profiles of equal equivalent width, 28.6 mÅ. Three absorption profiles with the same equivalent width — 28.6 milliångström, 1.72 km/s at 500 nm, matched to better than 0.1% by root-finding over the quadrature — differing in nothing but shape. Left: the cores, on a common velocity axis. Right: the same three normalised to their own half widths, on a logarithmic depth scale. The thermal profile is a Gaussian set by Fe's mass at 6000 K, 1.34 km/s; the collisional one a Lorentzian of γ = 2.28e-3 nm; the rotational one the classical kernel of a disc turning at v sin i = 1.73 km/s, which is exactly zero beyond 1.28 half widths and is the only one of the three with an edge. Matching the areas does not match the widths: the half widths are 1.11 km/s (thermal), 1.35 km/s (rotational), 0.68 km/s (collisional), a factor of 1.98 between the widest and the narrowest. At three half widths the collisional wing is 49 times the thermal one and at five it is 1.27·10⁶ times — six decades, which is why a line's shape stays diagnostic long after its width has stopped being so. 11% of the Lorentzian's own equivalent width lies beyond the right-hand panel's edge and is not drawn anywhere.

The same width for three different reasons

Thermal motion, rotation and collisions each widen an absorption line, and they can be tuned to areas that agree to a part in a thousand. What separates them is the shape, and the shape carries a rotation speed from one profile and a surface gravity from another.

starlight · Line formation
The Balmer maximum is at 9,870 K, and it is a maximum in temperature. What two absorption lines actually count, each normalised to its own maximum. The first curve is the fraction of all hydrogen sitting in n = 2 — the only hydrogen a Balmer line can absorb — which is a Boltzmann factor climbing with temperature multiplied by the neutral fraction falling with it. The product peaks at 9,870 K, where 35.2% of the hydrogen is still neutral and only 8.73·10⁻⁶ of all of it is in n = 2 at all. Below the peak there is plenty of hydrogen and almost none of it excited; above it there is plenty excited and almost none of it neutral. The second curve is the fraction of calcium that is singly ionised, which is what the Ca II K line counts, and it peaks at 6,335 K — cooler, because calcium gives up its first electron at 6.113 eV. At 6,000 K the Balmer curve is at 0.1% of its own maximum while Ca II is near its peak, and calcium is 4.5·10⁵ times rarer than hydrogen in the same gas. A spectrum in which Ca II K is the strongest line is not a spectrum of a calcium star. Reading it as one is precisely the error that had the Sun made of iron until 1925.

Why hydrogen's lines are strongest where hydrogen is not

A Balmer line counts the hydrogen atoms sitting in one particular excited state, and that population peaks near 10,000 K — where a third of the hydrogen has already been ionised away. The strength of a line is a thermometer, and reading it as an abundance put hydrogen at one per cent of the Sun until 1925.

starlight · Ionisation
742 kelvin between a dwarf and a supergiant, at the same ionisation. The fraction of calcium still neutral against temperature, for three surface gravities: a dwarf, a giant and a supergiant. The three curves are the same curve slid sideways. The Saha equation carries the electron pressure in its denominator, and the photospheric pressure follows the surface gravity as its square root — hydrostatic equilibrium gives a gas pressure of order g over the opacity, and the opacity in a cool star is set by the electrons themselves. So the pressure runs from 19 newtons a square metre in the dwarf down to 0.48 in the supergiant, a factor of 40, and the half-ionisation point moves from 4427 kelvin to 3685 — 742 kelvin apart. At fixed temperature the ionisation ratio goes as g^-0.50, exactly the square root the algebra requires. A star's luminosity class is a measurement of the density of its photosphere, read off which stage of an element the lines belong to.

A luminosity class is a density measurement

The Saha equation has an electron pressure in its denominator, and a supergiant's photosphere is forty times less dense than a dwarf's at the same temperature. So the same element sits in different ionisation stages in the two, the spectrum says which, and the second axis of stellar classification is a barometer.

starlight · Ionisation
Where titanium oxide comes apart, and what the pressure does to it. The fraction of titanium oxide dissociated into Ti + O, against temperature, for a gas of equal parts at 10, 300, 6000 N/m² of total pressure. The equilibrium is Saha's with a free atom in place of the free electron and the pair's reduced mass in place of the electron's — the two atoms' partial pressures multiplied together, divided by the molecule's, equal an equilibrium constant Kₚ(T) — which for equal abundances gives a dissociated fraction of √(Kₚ/(Kₚ+P)) exactly. A molecule is one particle becoming two, so pressure suppresses the reaction exactly as it suppresses ionisation — the half-dissociation point moves from 3145 K at 10 N/m² to 4164 K at 6000. The bond energy is 6.87 eV against hydrogen's ionisation potential of 13.6, which is why this happens at a third of the temperature. Rotational and vibrational partition functions are included, classically and harmonically; the atoms keep their ground-term weights.

A spectrum with no continuum left in it

Below about four thousand kelvin a photosphere stops being a gas of atoms. Titanium oxide, water and carbon monoxide take over, the same equilibrium settles how much of each survives with a bond energy where an ionisation potential used to be — and the bands are so crowded that the level every line depth is measured against is nowhere on the plate.

starlight · Ionisation

Named alongside it

The objects these essays reach for when they reach for this one.

Partition functionSaha equationElectron pressureIonisationLuminosity classSurface gravityAbsorption lineAbundanceApparent magnitudeBalmer seriesBlackbodyBolometric correction

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