Astronomy & Celestial Mechanics
the sky, computed
Concept

Abundance — where it appears

The amount of an element present, quoted as a number ratio against hydrogen rather than as a mass. It is read from the strengths of absorption lines through a curve of growth, so it is never measured directly and always depends on a model of the layer the lines formed in.

Named by 4 essays across one field — each of them below, with the objects they name alongside it.

The curve of growth. The equivalent width of an absorption line against the number of absorbers along the sight line, both logarithmic, computed by integrating a Voigt profile with damping parameter 0.005. Three regimes: the width grows in proportion to the abundance while the line is weak, then almost not at all for two decades once the core saturates, then as the square root once the damping wings dominate. A line measured in the middle stretch carries almost no information about the abundance, and most strong lines in a stellar spectrum are there.

How much of a line is not in its depth

An absorption line stops getting deeper long before it stops getting stronger. What keeps growing is its area, and the way the area depends on the number of absorbers has three distinct regimes over five decades — one of which carries almost no information at all.

starlight · Line formation The Balmer maximum is at 9,870 K, and it is a maximum in temperature. What two absorption lines actually count, each normalised to its own maximum. The first curve is the fraction of all hydrogen sitting in n = 2 — the only hydrogen a Balmer line can absorb — which is a Boltzmann factor climbing with temperature multiplied by the neutral fraction falling with it. The product peaks at 9,870 K, where 35.2% of the hydrogen is still neutral and only 8.73·10⁻⁶ of all of it is in n = 2 at all. Below the peak there is plenty of hydrogen and almost none of it excited; above it there is plenty excited and almost none of it neutral. The second curve is the fraction of calcium that is singly ionised, which is what the Ca II K line counts, and it peaks at 6,335 K — cooler, because calcium gives up its first electron at 6.113 eV. At 6,000 K the Balmer curve is at 0.1% of its own maximum while Ca II is near its peak, and calcium is 4.5·10⁵ times rarer than hydrogen in the same gas. A spectrum in which Ca II K is the strongest line is not a spectrum of a calcium star. Reading it as one is precisely the error that had the Sun made of iron until 1925.

Why hydrogen's lines are strongest where hydrogen is not

A Balmer line counts the hydrogen atoms sitting in one particular excited state, and that population peaks near 10,000 K — where a third of the hydrogen has already been ionised away. The strength of a line is a thermometer, and reading it as an abundance put hydrogen at one per cent of the Sun until 1925.

starlight · Ionisation A better measurement that made the model worse: 0.9 per cent in the sound speed. The fractional difference between the Sun's sound speed as its own oscillations measure it and as a structural model predicts it, against fractional radius. Zero would be agreement. The lower curve is the model built on the solar abundances used until the mid-2000s, and it hugs the axis: a part in a thousand across most of the interior, which was for a long time the best-tested piece of stellar physics anybody had. The upper curve is the same model with the abundances re-measured using three-dimensional atmospheres and without assuming local thermodynamic equilibrium — better measurements by every methodological standard, which lowered carbon, nitrogen and oxygen by around thirty per cent. The disagreement grows to 0.9 per cent, and it is not spread through the star: it peaks at 0.683 of the radius, just beneath the base of the convection zone at 0.713. The same substitution moves the model's own convection-zone base from 0.715 to 0.729, against a seismic value known to about a thousandth. What is being tested here is not really the abundances but what converts a composition into a structure, which is the opacity: the metals whose abundances fell are exactly the ones whose bound–free absorption dominates at those temperatures, and an opacity larger by some fifteen per cent near that boundary would restore the agreement. Laboratory measurements of iron at those conditions have since come in high by about that much, which is a satisfying result to have arrived at by way of a discrepancy in the sound speed of the Sun. The curves are published inversions and model differences rather than anything computed here; what the figure adds is where they peak and by how much.

A better measurement that made the model worse

The Sun's composition was re-measured with better atmospheres and better physics, and the carbon, nitrogen and oxygen abundances fell by about thirty per cent. The improved model then disagreed with the Sun's own oscillations by ten times as much as the model it replaced, and it still does.

starlight · Opacity A synthetic spectrum fitted with a line list that is missing the weak lines. Four ångströms of a simulated metal-line spectrum near 5000 Å at resolving power 20,000 and a signal-to-noise ratio of 200 (thin, noisy line), and the best-fitting synthesis (heavy line) computed from a line list that omits every line with a central optical depth below 0.15 — 137 of the 160 lines in the ten-ångström window, carrying 32 per cent of its total absorption. The fit adjusts one abundance for all the listed lines, with the continuum held at its true level; it returns an abundance 0.188 dex too high: the missing lines' absorption has nowhere to go but into the parameters the synthesis has. The residuals (below, offset) show the missing lines as dips that no parameter of the synthesis can fill — which is how an incomplete list announces itself at high resolution, and why it does not at low.

The lines a synthesis keeps pay for the ones it lacks

Modern abundance work fits a computed spectrum to a whole stretch of the observed one rather than measuring lines one at a time, and it averages away the errors in each line's laboratory data as it does so. It cannot average away a line that is not in its list. The absorption of the missing lines has to be put somewhere, and the fit puts it into the parameters it has — the abundance of the lines it knows, or the level of the continuum — in a direction set by which of the two it was allowed to move.

starlight · Line formation

Named alongside it

The objects these essays reach for when they reach for this one.

Equivalent widthOscillator strengthSolar abundance problemSystematic errorBalmer seriesBlendingBoltzmann distributionBound-free absorptionContinuum normalisationConvectionCurve of growthDamping wings

All concepts